By Oleg N. Chupakhin,Valery N. Charushin,Henk C. van der Plas

Nucleophilic fragrant substitution in carbo- and heteroaromatic platforms is a topic of substantial curiosity to chemists. This publication uniquely addresses the systematic research of an unlimited variety of nucleophilic substitutions of fragrant hydrogen.

  • Nucleophilic displacement of hydrogen (the S N/H reactions) in pi-deficient aromatics, reminiscent of nitroarenes, arene-metal complexes, and the like
  • Nucleophilic displacement of hydrogen in heterocyclic substrates corresponding to pyridines, their aza and benzo analogs, pyrylium and thiapyrylium cations, and different heterocycles
  • Mechanisms for the S N/H reactions (S N/H(AE), vicarious nucleophilic substitutions, and radical S N/H substitutions

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